Exam points & syllabus
Exam points
- Describe scattering observations with relative frequencies and link them to mostly empty atoms with small, dense, positively charged nuclei.
- State the historical nuclear model with concentrated mass and charge, and distinguish its supported claims from electron-level or orbit claims.
- Use A=Z+N in nuclide notation, reading A above Z and finding neutrons from A−Z rather than confusing nucleon and proton numbers.
- Exclude electrons from nucleon counts: an ion’s extra electrons change its charge but not A, Z or nuclear identity.
- Balance A and Z independently to identify unknown reaction nuclei or particles; supply both numbers when the marking point requires them together.
- Include incident neutrons and outgoing coefficients when balancing fission, and keep the assumed parent isotope consistent with the neutron count.
- For alpha decay, obtain the daughter proton number by subtracting two from the parent rather than confusing the mass change with the charge change.
- Describe observing absorption by passing white light through a gas and analysing the transmitted light; the result is dark lines on a continuous background.
- Explain line-spectrum evidence through specific photon frequencies, E=hf and electron-energy differences, rather than simply saying levels are discrete.
- Identify electrons as the atomic-transition particles; emission is a downward energy change releasing a photon, while absorption raises the atomic energy.
- Test absorption against an allowed gap from the specified initial state; being below ionization energy does not by itself make a photon absorbable.
- Draw the particular downward transition matching a photon’s energy and use the actual diagram labels rather than a corrupted flattened index.
- Count all accessible downward pairs, including intermediate transitions, while excluding levels above the specified excitation and checking distinct gaps.
- When a spectral count has a strict energy threshold, calculate each candidate gap and exclude a transition exactly equal to that threshold.
- Use E=hf=hc/λ with consistent units; subtract levels before converting eV to joules, and convert wavelength prefixes before substitution.
- For a longest wavelength or lowest frequency, choose the smallest allowed positive gap; shortest wavelength corresponds to the largest relevant gap.
- From an absorbed wavelength, compute hc/λ and identify both matching endpoint states; in a show-that emission task also demonstrate the matching gap.
- Relate spectrum positions to level gaps through the wavelength axis, including combined gaps and the possibility that only part of the spectrum is shown.
- Use spectra as evidence for changes in atomic modelling and distinguish this evidence for energy levels from scattering or nuclear reactions.
- Determine chemical composition by comparing observed element-specific stellar lines with laboratory spectra, explaining selective absorption when required.
- Use matching stellar dips and hydrogen emission peaks as evidence of hydrogen, while keeping an inferred main-sequence classification conditional.
- Confirm solar helium through observed lines matching helium; a proposed fusion model alone is not the requested empirical confirmation.
Covered syllabus points
Question 1
This question is in two parts. Part 1 is about the nuclear model of the atom and radioactive decay. Part 2 is about waves.
Part 1 Nuclear model of the atom and radioactive decay
Outline how the evidence supplied by the Geiger-Marsden experiment supports the nuclear model of the atom.
Question 1
Tritium may be produced by bombarding a nucleus of the isotope lithium-7 with a high-energy neutron. The reaction equation for this interaction is
Identify the proton number Z of X.
Question 1
This question is about atomic energy levels.
Question (a)
Outline a laboratory procedure for producing and observing the atomic absorption spectrum of a gas.
Question (b)
Describe the appearance of an atomic absorption spectrum.
Question (c)
Explain why the spectrum in (a) provides evidence for quantization of energy in atoms.
Question 1
This question is about energy level transitions.
Some of the electron energy levels for a hydrogen atom are shown.
Question (a)
A hydrogen atom is excited to the -1.51 eV level.
Question (i)
On the diagram, label using arrows all the possible transitions that might occur as the hydrogen atom returns to the ground state.
Question (b)
Monochromatic radiation is incident on gaseous hydrogen. All the hydrogen atoms are in the ground state. Describe what could happen to the radiation and to the hydrogen atoms if the incident photon energy is equal to
Question (i)
10.2 eV .
Question (ii)
9.0 eV .
Question 1
This question is about energy level transitions.
Some of the electron energy levels for a hydrogen atom are shown.
A hydrogen atom is excited to the -1.51 eV level.
State the energy in eV of the maximum wavelength photon emitted as the hydrogen atom returns to the ground state.
Question 1
The diagram shows a simplified energy-balance model for the Earth surface–atmosphere system.
The following data are given:
The primary energy source of the Sun is the proton-proton (p-p) chain of fusion reactions. Four protons and two electrons produce a helium nucleus together with neutrinos and gamma photons. The overall reaction is:
Outline how the presence of helium in the Sun can be confirmed empirically.